Heptan-1-Ol CAS 111-70-6 Gentanol; N-Heptanol; 1-Hydroxyheptane; Heptyl Alcohol

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Product origin: Changsha, Hunan, China
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Description
Heptan-1-ol CAS 111-70-6 Gentanol;n-Heptanol;1-Hydroxyheptane;Heptyl Alcohol
 
 
1-Heptanol Chemical Properties
Melting point -36 °C (lit.)
Boiling point 176 °C (lit.)
density 0.822 g/mL at 25 °C (lit.)
vapor pressure 0.5 mm Hg ( 20 °C)
refractive index n20/D 1.424(lit.)
FEMA 2548 | HEPTYL ALCOHOL
Fp 165 °F
storage temp. Store below +30°C.
solubility 1g/l
pka15.38±0.10(Predicted)
form Liquid
color Clear
OdorWeak alcoholic.
Relative polarity0.549
Odor Threshold0.0048ppm
explosive limit0.9%(V)
Water Solubility 2.85 g/L (100 ºC)
JECFA Number94
Merck 14,4661
BRN 1731686
Stability:Stable. Flammable. Incompatible with strong acids, strong oxidizing agents.
InChIKeyBBMCTIGTTCKYKF-UHFFFAOYSA-N
CAS DataBase Reference111-70-6(CAS DataBase Reference)
NIST Chemistry Reference1-Heptanol(111-70-6)
EPA Substance Registry System1-Heptanol (111-70-6)
 
Safety Information
Hazard Codes Xn,Xi
Risk Statements 20/21/22-36-52
Safety Statements 36-36/37/39-26
RIDADR 2810
WGK Germany 1
RTECS MK0350000
Autoignition Temperature662 °F
TSCA Yes
HazardClass 6.1(b)
PackingGroup III
HS Code 29051900
Hazardous Substances Data111-70-6(Hazardous Substances Data)
ToxicityLD50 orally in Rabbit: 500 mg/kg LD50 dermal Rabbit 2000 mg/kg
1-Heptanol Usage And Synthesis
DescriptionHeptyl alcohol has a faint, aromatic, fatty odor and a pungent, spicy taste. It may be synthesized by reduction of enanthic aldehyde, which is a distillation product of castor oil.
Chemical PropertiesHeptyl alcohol has a fragrant, woody, heavy, oily, faint, aromatic, fatty odor and a pungent, spicy taste.
Chemical Propertiescolourless liquid
OccurrenceReported found in a few essential oils, hyacinth, violet leaves, Litsea zeylanica Also reported found in apple, banana, citrus peel oils, orange juice, bilberry, cranberry, blueberry, other berries, currants, melon, papaya, peach, pear, pineapple, asparagus, peas, potato, mustard, cheeses, butter, milk, meats, hop oil, beer,  rum, bourbon whiskey, grape wines, cocoa, tea, flberts, pecans, peanuts, soybeans, passion fruit juice, olive, macadamia nuts, mango, tamarind, fgs, cardamom, rice, calamus, dill, corn, malt, kiwifruit, truffe, nectarine, crab, crayfsh, clams and other sources
Uses1-Heptanol have also been used in the fragrance industry due to its pleasant smell.
Production Methods1-Heptanol is produced by reacting hexenes with  in the oxo process or by the catalytic reduction of heptaldehyde. It has little commercial value except in fragrances and as an artificial flavoring agent.
PreparationBy reduction of enanthic aldehyde, which is a distillation product of castor oil.
Aroma threshold valuesDetection: 3 ppb.
Synthesis Reference(s)The Journal of Organic Chemistry, 57, p. 1061, 1992 DOI: 10.1021/jo00030a003
Synthesis, p. 701, 1979 DOI: 10.1055/s-1979-28800
General DescriptionWatery colorless liquid with a weak alcohol odor. Floats on water.
Reactivity ProfileHeptan-1-ol is an alcohol. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. They react with oxoacids and carboxylic acids to form esters plus water. Oxidizing agents convert them to aldehydes or ketones. Alcohols exhibit both weak acid and weak base behavior. They may initiate the polymerization of isocyanates and epoxides.
HazardCombustible.
Health HazardLow toxicity; liquid may irritate eyes.
Chemical ReactivityReactivity with Water No reaction; Reactivity with Common Materials: No reactions; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.
Purification MethodsShake the alcohol with successive lots of alkaline KMnO4 until the colour persists for 15minutes, then dry it with K2CO3 or CaO, and fractionally distil it. [Beilstein 1 IV 1731.]
 


Company Informations:

Hunan Yunbang Pharmaceutical Co., Ltd. (Yunbangpharm) located in Changsha High-tech Industrial Park, Hunan. It is a high-tech enterprise specializing in the research and development, production and sales of Pharmaceutical raw materials, Pharmaceutical intermediates(API) and Fine chemicals. Based in China, Yunbangpharm has been providing suitable solutions for many domestic,foreign pharmaceutical companies and traders. Excellent quality, good reputation and authentic price have won the praise of the majority of customers.
The company adheres to the corporate tenet of "We do not produce medicines, but help pharmaceutical companies make good medicines".

We can provide customers with customized processing, research and development services;
We can develop high-end Pharmaceutical and chemical products with high technical difficulties,high barriers and unique production processes;
We can provide 100 grams Grade, kilograms, and hundred kilograms of raw material pharmaceutical intermediates and other products.
We can perform -100°C to 300°C reaction.

R&D strength is the company's core competitiveness.Yunbangpharm has maintains a good cooperation relationship with many Universities and Research institutes locally, which can quickly transform R&D results into industrial production.

Our goal : To achieve the integrated upgrade of Pharmaceutical intermediates, raw materials and high-end chemical products, adhere to "serving pharmaceutical companies, creating our brands" to provide customers with high-quality and low-cost pharmaceutical and chemical products, realizing Win-win cooperation and common development.
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