Ethyl 3-methyl-3-phenylglycidate Product Name Ethyl 3-methyl-3-phenylglycidate
CAS 77-83-8
MF C12H14O3
MW 206.24
EINECS 201-061-8
MOL File 77-83-8.mol
Chemical Properties
Boiling point 272-275 °C(lit.) Density 1.087 g/mL at 25 °C(lit.) FEMA 2444 | ETHYL METHYLPHENYLGLYCIDATE refractive index n20/D 1.505(lit.) Flash point >230 °F storage temp. 2-8°C JECFA Number 1577 BRN 12299 CAS DataBase Reference 77-83-8(CAS DataBase Reference) NIST Chemistry Reference Glycidic acid, 3-methyl-3-phenyl, ethyl ester(77-83-8) EPA Substance Registry System Ethyl methylphenylglycidate (77-83-8)
Usage And Synthesis Chemical Properties
clear yellow liquid
Chemical Properties
Ethyl 3-Methyl-3-phenylglycidate exists as two optically active pairs of cis- and trans-isomers; each isomer has a characteristic odor . The commercial product is a racemic mixture of all four isomers and has a strong, sweetish, strawberry odor. The cis/trans ratio obtained in the Darzens condensation of acetophenone (R==CH3) and ethyl chloroacetatee depends on the base used in the reaction.
Chemical Properties
Ethyl methylphenylglycidate on dilution has a strong fruity odor suggestive of strawberry. It has a characteristic, slightly acid taste reminiscent of strawberry.
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